Publication:
The FT-IR spectroscopic investigation of transition metal(II) 4-aminopyridine tetracyanonickelate complexes

dc.contributorFen Edebiyat Fakültesi / Faculty of Letters and Sciences Fizik / Physicstr_TR
dc.contributor.authorAKYÜZ, SEVİM
dc.contributor.authorID10127tr_TR
dc.date.accessioned2018-08-31T12:32:50Z
dc.date.available2018-08-31T12:32:50Z
dc.date.issued1999-05-25
dc.description.abstractFT-IR spectra of M(4Apy)2Ni(CN)4 {where M=Mn, Co, Ni, Cu or Cd; 4Apy=4-aminopyridine} complexes are reported for the first time in the 400–4000 cm−1 range. The spectral features suggest that the compounds are similar in structure to the Hofmann-type complexes with infinite polymeric layers formed with Ni(CN)4−2 ions bridged by M(4Apy)2+2 cations and the ring nitrogen of the 4Apy is only involved in complex formation. However in some cases host complexes include H2O molecules as guest species which are found to be H-bonded to hydrogens of the amino group of 4Apy (N–H⋯OH2). The coordination effect on the 4Apy modes is analysed.tr_TR
dc.identifier482-483tr_TR
dc.identifier482-483tr_TR
dc.identifier482-483tr_TR
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(98)00638-3
dc.identifier.urihttps://hdl.handle.net/11413/2580
dc.language.isoen_UStr_TR
dc.publisherElseviertr_TR
dc.relationJournal of Molecular Structuretr_TR
dc.subjectFT-IRtr_TR
dc.subjectAminopyridinetr_TR
dc.subjectHofmann type complexestr_TR
dc.subjectTetracyanonickelatetr_TR
dc.subjectTransition metaltr_TR
dc.titleThe FT-IR spectroscopic investigation of transition metal(II) 4-aminopyridine tetracyanonickelate complexestr_TR
dc.typeArticletr_TR
dspace.entity.typePublication
relation.isAuthorOfPublication70600e97-ae14-4ca5-b357-0fd647a25331
relation.isAuthorOfPublication.latestForDiscovery70600e97-ae14-4ca5-b357-0fd647a25331

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