Publication: Phase transformation in the system TlBi(Te1-xSex)(2)
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Date
2004-04
Authors
Chrissaris, K.
Vinga, E. S.
Özer, Mehmet
Paraskevopoullos, K. M.
Polychroniadis, E. K.
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-V C H Verlag GMBH, Po Box 10 11 61, D-69451 Weinheim, Germany
Abstract
TlBiTe2 and TlBiSe2 -that are ternary analogs of the IV-VI semiconductors-, although they crystallize in the same space group R (3) over barm (D-3d(5)), exhibit different behaviour during heating. The observed phase transformation depends on Se content (x) in the system TIBi(Te1-xSex)(2) and the transformation disappears by increasing Se content after a certain value (x=0.25). This dependence is examined through the analysis of the DSC non-isothermal measurements and an attempt for the explanation of the observed behaviour is undertaken through the consideration of off - center atoms. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Description
Keywords
phase transformation, off-center, DSC, narrow gap, chalcogenides, plasma, Ictac Kinetics Project, Computational Aspects, Tlbite2, Growth