Publication:
An Infrared and Raman Spectroscopic Study of Metal II Di 2 Methylpyridine Tetracyanonickelate Complexes

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Date

1985-12

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Kluwer Academic Publishers

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Abstract

The results of an infrared and Raman spectroscopic study are reported for two new metal 2-methylpyridine tetracyanonickelate complexes, M(C6H7N)2Ni(CN)4, M=Ni or Cd. Their structure consists of corrugated polymeric layers of {M-Ni(CN)4}∞ with 2-methylpyridine molecules bound directly to the metal (M). These complexes can act as host lattices in the formation of inclusion compounds with dioxane guest molecules.

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Keywords

2-methylpyridine, tetracyanonickelate complex, inclusion compound, infrared and Raman spectra

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