Fen Edebiyat Fakültesi / Faculty of Letters and Sciences Fizik / PhysicsDavies, J. Eric D.AKYÜZ, SEVİMAKYÜZ, ZEKİ TANIL2018-08-312018-08-311996-030923-07501573-1111https://doi.org/10.1007/BF01029935https://hdl.handle.net/11413/2565The FT-IR and Raman spectra are reported of M(4,4′-bipyridyl)Ni(CN)4·nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline;n = 0–2) clathrates. The host structure consists of a three-dimensional rigid lattice formed by infinite polymeric layers of {M-Ni(CN)4}∞ and 4,4′-bipyridyl bridges between the metal (M) atoms of the adjacent polymeric layers. Bidentate 4,4′-bipyridyl molecules are found to be centrosymmetric in the structure.en-USTetracyanonickelate compoundsbenzene clathrateaniline clathrateIR and Raman spectra4,4′-bipyridyl complexesArticle